Title of article
Improved solubility of β-cyclodextrin inclusion complexes by using liquid ammonia as a solvent and the possibility of asymmetric reduction
Author/Authors
Matsuoka، نويسنده , , Koji and Takahashi، نويسنده , , Hiroyuki and Saito، نويسنده , , Yosuke and Terunuma، نويسنده , , Daiyo and Kuzuhara، نويسنده , , Hiroyoshi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
4
From page
373
To page
376
Abstract
Dramatic improvement in the poor solubility of β-cyclodextrin (β-CD) and its inclusion complexes in water was achieved by using liquid ammonia (liq. NH3) instead of water as the solvent. Asymmetric NaBH4 reduction of the carbonyl groups of the inclusion complexes in liq. NH3 was examined in a homogeneous condition to give the corresponding alcohols with moderate chirality.
Keywords
Liquid ammonia , asymmetric reduction , Inclusion complexes , Cyclodextrins
Journal title
CARBOHYDRATE POLYMERS
Serial Year
2002
Journal title
CARBOHYDRATE POLYMERS
Record number
1612373
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