Title of article
Formation of cyclooctatriene and bicyclooctadiene through regioselective intermolecular (2 + 2) photocycloaddition of benzoic acids to allyl alcohol in water
Author/Authors
Itou، نويسنده , , Tatsuya and Yoshimi، نويسنده , , Yasuharu and Kamiya، نويسنده , , Kazuyuki and Takedani، نويسنده , , Hitoshi and Morita، نويسنده , , Toshio and Hatanaka، نويسنده , , Minoru، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
5
From page
235
To page
239
Abstract
The regioselective intermolecular (2 + 2) photocycloaddition of the sodium salt of benzoic acids 1 to allyl alcohol 2 proceeded in water to afford cyclooctatrienes 3 and bicyclooctadienes 4. The efficiency and product distribution of this photoreaction were strongly influenced by the substituent of benzoic acid and solvent polarity. The photocycloaddition of benzoic acids in water is an environmentally friendly method for the preparation of cyclooctatriene and bicyclooctadiene.
Keywords
Cyclooctatriene , Bicyclooctadiene , + , 2) photocycloaddition , water , Benzoic acid , Regioselective intermolecular (2 , Allyl alcohol
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Serial Year
2009
Journal title
Journal of Photochemistry and Photobiology:A:Chemistry
Record number
1616866
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