Molecular weight, chain profile of rice amylopectin and starch pasting properties

Differences in fine structure, average molecular size of amylopectin (AP) as well as clarity of the AP solution from indica waxy rice and high amylose (HAM) rice were examined. Despite similar amylose content (AM), rice starches displayed different pasting properties. Waxy APs had higher values of both number–average and weight–average molecular weight ( M n ¯ and M w ¯ ) but lower values of intrinsic viscosity [η], compared to HAM APs. HAM APs had higher values of average chain length ( CL ¯ ), average external chain length ( ECL ¯ ), and a proportion of DP ≥ 37. Statistical correlations of mol proportions of debranched AP, branching parameters, and molecular weight of AP were calculated. The study showed that starch pasting properties and clarity of AP solutions were influenced by molecular weight and branching characteristics of AP.