Numerical calculation on the porosity distribution and diffusion coefficient of interfacial transition zone in cement-based composite materials

Based on the cement particles distribution characteristic of interfacial transition zone (ITZ) in cement-based composite materials and modified powers model, a numerical calculation model is proposed to predict the porosity distribution, average porosity and effective diffusion coefficient of chloride ions in ITZ. The model takes into account the influence of water-to-cement ratio, the thickness of ITZ and the degree of hydration on the porosity distribution of ITZ. The results show that the ratio of the capillary porosity of ITZ to that of bulk cement paste (ϕITZ/ϕB) and the ratio of the diffusion coefficients of chloride ions in ITZ to that in bulk cement paste (DITZ/DB) are almost consistent with those in published papers. In addition, the results of numerical calculation further confirm the diffusion coefficient of ITZ is 10 times as much as that of bulk cement paste.