Title of article
Two-dimensional hexagonal hydrogen-bonded network with triangle-like large cavities: hexakis(4-carboxyphenyl)benzene
Author/Authors
Kobayashi، نويسنده , , Kenji and Shirasaka، نويسنده , , Toshiaki and Horn، نويسنده , , Ernst and Furukawa، نويسنده , , Naomichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
89
To page
93
Abstract
Hexakis(4-carboxyphenyl)benzene (1) as a radially functionalized hexagonal host was synthesized by the Co-catalyzed cyclotrimerization of diarylacetylene. When recrystallized from MeOH, host 1 self-assembles into a two-dimensional hexagonal hydrogen-bonded network having triangle-like large cavities (one side of ca. 15.2 إ), each of which is filled with guest molecules without interpenetration of the crystal lattice.
Keywords
Carboxylic acid derivatives , Hydrogen bonding , Supramolecular chemistry , X-ray crystallography , carboxylic acids
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1635957
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