Title of article
Phosphine catalyzed aldol reaction between ketene silyl acetals and aldehydes: nucleophilic O–Si and C–Si bond cleavage by phosphines
Author/Authors
Matsukawa، نويسنده , , Satoru and Okano، نويسنده , , Naoko and Imamoto، نويسنده , , Tsuneo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
103
To page
107
Abstract
A highly nucleophilic phosphine, tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP), catalyzes the aldol reaction between ketene silyl acetals and aldehydes to give the corresponding aldol products in good to high yields. This reaction is considered to proceed through naked enolates produced by nucleophilic O–Si and C–Si bond cleavage.
Keywords
phosphines , naked enolates , aldol reactions
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1635962
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