Author/Authors :
See Waters، نويسنده , , Marjorie and Cowen، نويسنده , , Jennifer A and McWilliams، نويسنده , , J.Christopher and Maligres، نويسنده , , Peter E and Askin، نويسنده , , David، نويسنده ,
Abstract :
Aryl alkynols provide a convenient entry into α-hydroxyketones via thiol addition followed by hydrolysis. Thiols have been added to several non-activated alkynes under mild, basic conditions. A coordinating functional group in close proximity to the triple bond facilitates this reaction.
Keywords :
Vinyl sulfides , hydroxyketones , neighboring group effects , Propargylic alcohols
