Title of article
A convenient route to keto-glycosyl phosphates
Author/Authors
Naundorf، نويسنده , , Andreas and Natsch، نويسنده , , Stefan and Klaffke، نويسنده , , Werner، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
189
To page
192
Abstract
The reagent combination, ruthenium dioxide/sodium periodate/benzyltriethyl ammonium chloride in dichloromethane/aqueous bicarbonate buffer simultaneously oxidises alcohol functions in the sugar ring and glycosyl H-phosphonates to yield keto-glycosyl phosphates. These can be coupled to the respective nucleoside diphosphates to render biosynthetically relevant sugar metabolites and derivatives thereof, useful for further investigation of the polysaccharide biosynthesis in bacteria and plants.
Keywords
Ruthenium , carbohydrates , Oxidation , phosphates
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1635995
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