Title of article :
Expedient synthesis of (+)-trans-5-allylhexahydroindolizidin-3-one
Author/Authors :
Potts، نويسنده , , Deirdre and Stevenson، نويسنده , , Paul J. and Thompson، نويسنده , , Norris، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
Treatment of the bicyclic iminium ion derived from 5-methoxyhexahydroindolizidin-3-one with allyltrimethylsilane gave exclusively the diastereoisomer in which the allyl group was axial. This substrate is a useful precursor to 5-propyl-3-alkylindolizidine alkaloids.
Keywords :
pyroglutamate , 1 , 3-allylic strain , indolizidine , N-acyliminium ion
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
