Title of article
Synthesis of naphthyl C-glycosides of rearranged tri-O-benzyl-2-deoxy-d-glucose
Author/Authors
Brimble، نويسنده , , Margaret A and Brenstrum، نويسنده , , Timothy J، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
1107
To page
1110
Abstract
C-Glycosylation of 3-bromonaphthol 4 with benzyl-protected glycosyl donor 19 afforded rearranged bicyclic acetal 24 in which the glycosyl donor had undergone an unusual 1,6-hydride shift. Use of the regioisomeric 2-bromonaphthol 6 with the same glycosyl donor 19 afforded the expected β-C-glycoside 22.
Keywords
C-Glycosides , 6-hydride shift , pyranonaphthoquinones , naphthols , 1
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636428
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