Title of article
Umpolung of the reactivity of allylsilanes. Palladium(II) catalyzed cyclization of allylsilyl alcohols: a new route to substituted 2-vinyltetrahydrofurans
Author/Authors
Macsلri، نويسنده , , Istvلn and Szabَ، نويسنده , , Kلlmلn J.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
1119
To page
1122
Abstract
Functionalized allylsilanes 1–4 undergo palladium(II) catalyzed ring closure to afford 4- and/or 5-substituted 2-vinyltetrahydrofurans (5–8) under mild conditions. The catalytic reactions proceed through (η3-allyl)palladium intermediates formed by palladadesilylation of the allylsilane substrates.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1636431
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