Title of article
New diphosphinite ligands derived from mannitol for rhodium catalyzed enantioselective hydrogenation of ketones
Author/Authors
Naili، نويسنده , , Said and Suisse، نويسنده , , Isabelle and Mortreux، نويسنده , , André and Agbossou، نويسنده , , Francine and Ait Ali، نويسنده , , Mustapha and Karim، نويسنده , , Abdallah، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
2867
To page
2870
Abstract
We have developed new electron rich chiral bisphosphinites from mannitol. The new ligands have been found to be efficient chiral auxiliaries for rhodium catalyzed hydrogenation of functionalized ketones leading to hydroxy compounds in up to 86% ee.
Keywords
ketones , diphosphanes , Enantioselective hydrogenation , Rhodium
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637080
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