Title of article
Reaction of 3-trimethylsilyloxy-2-aza-1,3-dienes with zirconocene: a transition metal promoted retro-Brook rearrangement
Author/Authors
Gandon، نويسنده , , Vincent and Bertus، نويسنده , , Philippe and Szymoniak، نويسنده , , Jan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
3053
To page
3056
Abstract
2-Aza-1,3-dienes bearing trimethylsilyloxy group at C3 undergo an unusual zirconium-mediated retro-Brook rearrangement to produce, after hydrolysis, silylated amides. Both [1,3]- and [1,4]-oxygen to carbon silyl migrations are observed depending on the substrate structure.
Keywords
Brook , aza compounds , Rearrangements , zirconium and compounds
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637187
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