Title of article
Preparation of functionalized alkenylmagnesium bromides via a bromine–magnesium exchange
Author/Authors
Thibonnet، نويسنده , , Jérôme and Knochel، نويسنده , , Paul، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
3319
To page
3322
Abstract
α-Bromonitriles, such as 1, 2 or the α-bromosulfone 3, undergo a smooth bromine–magnesium exchange with isopropylmagnesium bromide furnishing new functionalized organomagnesium species which react smoothly with various electrophiles like Me3SiCl, Bu3SnCl, allyl bromides, aldehydes, ketones or acid chlorides providing the expected products of type 7, 8 or 9.
Keywords
Nitrile , Sulfone , Magnesium , functionalized organometallics
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637345
Link To Document