Title of article :
Novel 1,3-sulfonyl shift and [4+2] cycloaddition reaction of N-allenyl sulfonamide promoted by allylsilane
Author/Authors :
Horino، نويسنده , , Yoshikazu and Kimura، نويسنده , , Masanari and Naito، نويسنده , , Makoto and Tanaka، نويسنده , , Shuji and Tamaru، نويسنده , , Yoshinao، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
The thermal reaction of allylsilanes and 5,5-dimethyl-3-tosyl-4-vinylidene-1,3-oxazolidin-2-one (1) at 80–100°C selectively furnishes tetrahydropyridine derivatives 5. The reaction involves a novel 1,3-sulfonyl shift as the key step.
Keywords :
Rearrangements , silicon and compounds , Cycloadditions , Allenes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
