Title of article
Rhodium-catalysed racemisation of N-acyl α-amino acids
Author/Authors
Hateley، نويسنده , , Martin J and Schichl، نويسنده , , Daniel A and Kreuzfeld، نويسنده , , Hans-Jِrn and Beller، نويسنده , , Matthias، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
3821
To page
3824
Abstract
The first transition metal-catalysed racemisation of N-acyl α-amino acids, which is of importance for kinetic resolution processes, is described. Enantiomerically pure N-acyl α-amino acids were efficiently racemised under mild conditions using various rhodium complexes as catalysts, e.g. [Rh(cod)Cl]2, in the presence of phosphines.
Keywords
Rhodium , Racemisation , N-acyl ?-amino acids , tricyclohexylphosphine
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637623
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