Author/Authors :
Chackalamannil، نويسنده , , Samuel and Doller، نويسنده , , Dar??o and Clasby، نويسنده , , Martin and Xia، نويسنده , , Yan and Eagen، نويسنده , , Keith and Lin، نويسنده , , Yan and Tsai، نويسنده , , Hsing-An and McPhail، نويسنده , , Andrew T.، نويسنده ,
Abstract :
An efficient, multigram-scale synthesis of dihydronaphthofuranone 1 using a novel aryl intramolecular Diels–Alder reaction of propargyl trans-cinnamate 8 is described. Catalytic reduction of 1 gave the cis-fused tetrahydronaphthofuranone derivative 2.
Keywords :
perhydronaphthofuranone , dihydronaphthofuranone , tetrahydronaphthofuranone , intramolecular Diels–Alder reaction , aryl intramolecular Diels–Alder reaction