Title of article
Conjugate addition to diethyl azodicarboxylate under organic-perfluorinated biphasic homogeneous catalysis by nickel(II) species
Author/Authors
Meseguer، نويسنده , , Miriam and Moreno-Maٌas، نويسنده , , Marcial and Vallribera، نويسنده , , Adelina، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
3
From page
4093
To page
4095
Abstract
The nickel(II) complex of the Schiff base of salicylaldehyde and 4-perfluorodecylaniline catalyzes the conjugate addition of β-diketones to electron-deficient substrates. Electrophilic amination with azodicarboxylate affords quaternary centers. The catalyst is recovered in solution and reutilized. Isolation of reaction products is very simple and does not require chromatography.
Keywords
Michael reactions , Catalysis , Nickel(II) , amination
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637756
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