Title of article
Palladium-catalyzed [2+2] cycloaddition of allylic acetates and norbornene
Author/Authors
Tsukada، نويسنده , , Naofumi and Sato، نويسنده , , Tetsuo and Inoue، نويسنده , , Yoshio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
4181
To page
4184
Abstract
Palladium-catalyzed reaction of norbornene with allyl acetate gave 3-methylenetricyclo[4.2.1.02,5]nonane 1 and 2-methylene-3-vinylnorbornane 2 in high yields. The substituents on allyl acetate strongly influenced the selectivity. In the reactions of 1- or 3-substituted allyl acetates, cycloadducts corresponding to 1 were obtained exclusively. Use of methallyl acetate gave solely a diene corresponding to 2.
Keywords
allylation , Catalysis , cycloaddition
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637797
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