Title of article
Copper-catalyzed aerobic oxidation of alcohols under fluorous biphasic conditions
Author/Authors
Bodo Betzemeier، نويسنده , , Bodo and Cavazzini، نويسنده , , Marco and Quici، نويسنده , , Silvio and Knochel، نويسنده , , Paul، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
4343
To page
4346
Abstract
A catalytic amount of perfluoroalkyl substituted bipyridine 1 (2 mol%), CuBr·Me2S (2 mol%) and TEMPO (3.5 mol%) allow the oxidation of various alcohols to aldehydes and ketones in a fluorous biphasic system of chlorobenzene and perfluorooctane directly with oxygen. The catalyst can be used for several reaction runs without a loss of reactivity.
Keywords
Copper , Fluorous phase , bipyridine , TEMPO , Oxidation
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1637861
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