Title of article :
Radical cleavage of a β-hydroxy azide: a reversal of regioselectivity in the oxidative fragmentation of hydroindoles
Author/Authors :
Wipf، نويسنده , , Peter and Mareska، نويسنده , , David A.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
Treatment of hydroindole 17 with PhI(OAc)2/I2 leads to oxidative fragmentation of the β-hydroxy azide moiety and results in the exclusive formation of keto nitrile 18 via radical cleavage of the lateral ring C–C bond.
Keywords :
regioselective oxidative fragmentation , hydroxy azide , keto nitrile
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
