Title of article
Chiral ligand-controlled diastereoselectivity and regioselectivity in palladium(0)-catalysed allylations
Author/Authors
Pyne، نويسنده , , Stephen G. and Dong، نويسنده , , Zemin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
5387
To page
5391
Abstract
Diastereoselective allylations can be achieved on an epimeric mixture of optically active allylic benzoates having a fixed stereogenic centre allylic to the π-system using chiral ligands. The regiochemistry of these reactions is controlled by the chiral ligand and is different for the different diastereomeric complexes.
Keywords
PALLADIUM , Regiochemistry , allylic amine , diastereoselection , Malonate , chiral ligand , Catalysis , allylation
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638214
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