Title of article
Highly efficient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation
Author/Authors
Longmire، نويسنده , , James M and Wang، نويسنده , , Bin and Zhang، نويسنده , , Xumu Zhang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
5435
To page
5439
Abstract
A new phosphine ligand has been synthesized and employed in the Pd-catalyzed alkylation of 2-cyclohexenyl esters. A very efficient resolution of 2-cyclohexenyl acetate was observed during alkylation. In addition, the reactivity and enantioselectivity showed a strong dependence on the acetate salt with the BSA/MOAc (M=alkali metal) base system during alkyation of cyclohexenyl carbonate.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638225
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