Title of article :
Formation and structural features of novel cage compounds with a pentacyclo[6.4.0.03,7.04,11.05,10]dodecane skeleton via photolysis of [33](1,3,5)cyclophane
Author/Authors :
Matohara، نويسنده , , Kumi and Lim، نويسنده , , Chultack and Yasutake، نويسنده , , Mikio and Nogita، نويسنده , , Rika and Koga، نويسنده , , Toru and Sakamoto، نويسنده , , Youichi and Shinmyozu، نويسنده , , Teruo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
The photolysis of [33](1,3,5)cyclophane 8 in MeOH:2N HCl (17:1 v/v) afforded new polycyclic caged dimethoxy and methoxy–hydroxy compounds 12 and 13 with a novel pentacyclo[6.4.0.03,7.04,11.05,10]dodecane skeleton 7, in addition to methyl ether 9c with the previously reported skeleton 6. The unique structural features of 12 and 13 were elucidated by X-ray structural analysis.
Keywords :
Photolysis , cyclophanes , polycyclic cage compounds , hexaprismane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
