Title of article
New synthesis of α-acyl imines by radical-mediated group-transfer imidoylation of acyl tellurides with isonitriles
Author/Authors
Yamago، نويسنده , , Shigeru and Miyazoe، نويسنده , , Hiroshi and Sawazaki، نويسنده , , Takashi and Goto، نويسنده , , Ryuta and Yoshida*، نويسنده , , Jun-ichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
7517
To page
7520
Abstract
Acyl radicals generated from either acyl tellurides or alkyl tellurides and carbon monoxide react with isonitriles to give α-acyl-substituted imidoyl tellurides in good to excellent yield. Hydrolysis of the product under oxidative conditions provides the corresponding α-acyl amides.
Keywords
radicals and radical reactions , Isocyanides , imidic acids and derivatives , carbonylation
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639045
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