• Title of article

    A radical approach to araliopsine and related quinoline alkaloids using manganese(III) acetate

  • Author/Authors

    Bar، نويسنده , , Gregory N. Parsons، نويسنده , , Andrew F and Thomas، نويسنده , , C.Barry، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    7751
  • To page
    7755
  • Abstract
    Reaction of 4-hydroxy-1-methyl-2(1H)-quinolone 3 with electron-rich alkenes and manganese(III) acetate produces tricyclic quinoline alkaloids, including araliopsine 1, in one-pot reactions. This combined intermolecular addition–cyclisation reaction produces angular and/or linear tricycles and the regioselectivity of the cyclisation is shown to depend on whether alkyl or aryl substituents are attached to the alkene.
  • Keywords
    manganese and compounds , Quinolines , radicals and radical reactions , Alkaloids
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1639160