Title of article
Solubilized zirconocene dihydride as a promotor of alkene coupling reactions
Author/Authors
Wipf، نويسنده , , Peter and Wang، نويسنده , , Xiaodong، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8237
To page
8241
Abstract
The THF-soluble bis(methoxyethyl)zirconocene dihydride 3 displayed novel reactivity patterns and was used to reductively couple alkenes, dienes, and enynes. A plausible mechanism involves the formation of a 14-electron zirconium(II) and zirconacyclopentane species.
Keywords
reductive cyclization , intra- and intermolecular coupling , zirconium(II) , zirconocene dihydride
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639433
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