Title of article :
Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis
Author/Authors :
Dang، نويسنده , , Hai-Shan and Roberts، نويسنده , , Brian P.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
Polarity-reversal catalysis by thiols has been applied to provide an efficient method for the conversion of appropriate 1,2-diols into less or similarly stable diastereoisomers by epimerisation of their acetonides under radical-chain conditions.
Keywords :
radicals and radical reactions , thiols , Diols , isomerisation , carbohydrates , Catalysis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
