Title of article
Development of a catalytic cycle for the generation of C1-glycosyl carbanions with Cp2TiCl2: application to glycal synthesis
Author/Authors
Hansen، نويسنده , , Thomas and Daasbjerg، نويسنده , , Kim and Skrydstrup، نويسنده , , Troels، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
8645
To page
8649
Abstract
A catalytic cycle has been developed for the conversion of glycosyl halides to their corresponding glycals using Cp2TiCl2. This process can be effectively used with only 30% of the in situ generated single electron reducing agent in contrast to the 2 equivalents normally employed.
Keywords
anomeric radicals , Electron transfer , Titanium , glycosyl halides , Anions
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1639717
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