• Title of article

    A unique case of face diastereoselectivity in the Michael addition reactions between Ni(II)-complexes of glycine and chiral 3-(E-enoyl)-1,3-oxazolidin-2-ones

  • Author/Authors

    Soloshonok*، نويسنده , , Vadim A and Cai، نويسنده , , Chaozhong and Hruby *، نويسنده , , Victor J، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    9645
  • To page
    9649
  • Abstract
    The origin of virtually complete face diastereoselectivity in the organic base-catalyzed, room temperature Michael addition reactions between Ni(II)-complexes of Schiff bases of glycine and chiral 3-(E-enoyl)-4-substituted-1,3-oxazolidin-2-ones was shown to stem from the unusual mode of steric interactions in determining the corresponding transition state.
  • Keywords
    asymmetric synthesis , Michael additions , Nickel(II) complex , amino acids , oxazolidin-2-ones
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1640390

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1640390