Title of article
Asymmetric induction through the use of remote covalent and ionic chiral auxiliaries in the solid state photochemistry of 2-benzoyladamantane-2-carboxylic acid derivatives
Author/Authors
Cheung، نويسنده , , Eugene and Netherton، نويسنده , , Matthew R and Scheffer، نويسنده , , John R and Trotter، نويسنده , , James and Zenova، نويسنده , , Alla، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
9673
To page
9677
Abstract
Attachment of chiral auxiliaries to 2-benzoyladamantane-2-carboxylic acid, either covalently through ester formation with optically pure alcohols, or ionically via salt formation with optically pure amines, leads to substrates whose irradiation in the crystalline state affords chiral rearranged photoproducts in ≥96% diastereo- and enantiomeric excess.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1640407
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