Title of article :
Conversion of α,β-unsaturated ketones into α-hydroxy ketones using an MnIII catalyst, phenylsilane and dioxygen: acceleration of conjugate hydride reduction by dioxygen
Author/Authors :
Magnus، نويسنده , , Philip and Payne، نويسنده , , Andrew H and Waring، نويسنده , , Michael W. and Scott، نويسنده , , David A and Lynch، نويسنده , , Vince، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
Treatment of a variety of α,β-unsaturated ketones with Mn(dpm)3 (3 mol%)/PhSiH3 (1.3 equiv.)/isopropyl alcohol/O2, followed by reductive work-up with P(OEt)3 resulted in the formation of α-hydroxyketones.
Keywords :
?-Hydroxyketone , Dioxygen , manganese(III) , Phenylsilane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
