• Title of article

    Cu(I)-assisted carboncarbon bond forming reactions of γ,γ-dialkoxyallylic zirconium species: a new versatile homoenolate equivalent of propionate

  • Author/Authors

    Sato، نويسنده , , Azusa and Ito، نويسنده , , Hisanaka and Yamaguchi، نويسنده , , Yusuke and Taguchi، نويسنده , , Takeo، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    10239
  • To page
    10243
  • Abstract
    In the presence of CuCN, reaction of γ,γ-dialkoxyallylic zirconium species 1 with acyl chloride or allylic phosphates proceeded at the α-position of 1 to give alkanoates 3 after aqueous work-up. The ketene dialkylacetal moiety in the coupling products 2 can be used for further bond forming reaction with electrophiles such as nitrosobenzene, nitrostyrene or trichloroacetylisocyanate.
  • Keywords
    allyl cuprate , ?-dialkoxyallylic zirconium , homoenolate , ketene acetal , ?
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2000
  • Journal title
    Tetrahedron Letters
  • Record number

    1640776

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1640776