Title of article
Studies on the reactions of α,β-enones with allyl indium reagent; effects of TMSCl as promoter on regioselectivity
Author/Authors
Lee، نويسنده , , Phil Ho and Ahn، نويسنده , , Hyosoon and Lee، نويسنده , , Kooyeon and Sung، نويسنده , , Sun-Young and Kim، نويسنده , , Sunggak and Jon، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
37
To page
39
Abstract
Regioselectivity on the reactions of α,β-enones with allyl indium reagents in the presence of TMSCl was systematically studied. 2-Cyclohexen-1-one, (R)-carvone, 2-cyclohepten-1-one and chalcone produced 1,4-addition products in good yields, whereas 2-cyclopenten-1-one, 2-methylcyclopenten-1-one, 4,4-dimethylcyclohexen-1-one and acyclic α,β-enones afforded 1,2-addition products.
Keywords
Indium , Michael reaction , Promoter
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1640875
Link To Document