Title of article
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulfide: determination of rate parameters by laser flash photolysis
Author/Authors
Romashin، نويسنده , , Yuri N and Liu، نويسنده , , Michael T.H and Bonneau، نويسنده , , Roland، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
207
To page
209
Abstract
Reaction of arylchlorodiazirines with trimethylenesulfide gives a mixture of aryldi(3-chloropropyl)thioacetal and aryl(2-propenyl)(3-chloropropyl)thioacetal in a good yield. The reaction goes through a formation of a sulfur ylide as an intermediate. Rate constants have been determined using laser flash photolytic techniques.
Keywords
Carbene , trimethylene sulfide , Laser flash photolysis , Kinetics , Sulfur ylide , Diazirine , Thioacetal
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1641020
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