Title of article
Regio- and stereoselective installation of alkyl groups onto cis 4-cyclopentene-1,3-diol monoacetate by using reagents derived from alkylmagnesium halides
Author/Authors
Ito، نويسنده , , Michiko and Murugesh، نويسنده , , Modachur G. and Kobayashi، نويسنده , , Yuichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
5
From page
423
To page
427
Abstract
Reaction of cis 4-cyclopentene-1,3-diol monoacetate with alkyl reagents derived from RMgX and CuCN furnished either trans 4-alkyl-2-cyclopenten-1-ols (1,4-isomers) or trans 2-alkyl-3-cyclopenten-1-ols (1,2-isomers) depending upon the stoichiometry of RMgX/CuCN and the solvents used (Et2O or THF).
Keywords
copper and compounds , Alkylation , cyclopentenes , coupling reactions , Grignard reactions/reagents
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1641191
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