Title of article
The first total synthesis of (±)-2-thiocyanatoneopupukeanane based on a pinacol-type rearrangement
Author/Authors
Uyehara، نويسنده , , Tadao and Onda، نويسنده , , Kayoko and Nozaki، نويسنده , , Naoko and Karikomi، نويسنده , , Michinori and Ueno، نويسنده , , Masako and Sato، نويسنده , , Toshio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
699
To page
702
Abstract
The racemic mixture of 2-thiocyanatoneopupukeanane, a marine sesquiterpene-thiocyanate with a tricylo[4.3.1.03,7]decane skeleton, was prepared through a pinacol-type rearrangement of a bicyclo[2.2.2]oct-5-en-2-ol giving a bicyclo[3.2.1]oct-6-en-2-one derivative and an aldol reaction leading to the neopupukeanane framework.
Keywords
Marine metabolites , Rearrangements , Terpenes , aldol reactions , bicyclic aliphatic compounds , Terpenoids
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1641409
Link To Document