• Title of article

    Prenyl and geranyl phenyl sulfone, a new carbon nucleophile for Mitsunobu-type alkylation

  • Author/Authors

    Uemoto، نويسنده , , Kaori and Kawahito، نويسنده , , Atsuko and Matsushita، نويسنده , , Noriko and Sakamoto، نويسنده , , Izumi and Kaku، نويسنده , , Hiroto and Tsunoda، نويسنده , , Tetsuto، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    905
  • To page
    907
  • Abstract
    Cyanomethylenetrimethylphosphorane (CMMP), a new Mitsunobu reagent developed recently by the authors, mediated the alkylation of prenyl and geranyl phenyl sulfone with primary and secondary alcohols quite efficiently. Utilizing geranyl phenyl sulfone, norfaranal, an analog of the unique trail pheromone produced by Pharaohʹs ant, was synthesized in a short number of steps.
  • Keywords
    Mitsunobu reactions , Phosphorane , Sulfones , pheromone
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1641578