Title of article
Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica
Author/Authors
Ryu، نويسنده , , Ilhyong and Kreimerman، نويسنده , , Sergio and Niguma، نويسنده , , Tatsuro and Minakata، نويسنده , , Satoshi and Komatsu، نويسنده , , Mitsuo and Luo، نويسنده , , Zhiyong and Curran، نويسنده , , Dennis P، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
947
To page
950
Abstract
A simple free-radical method for the preparation of a variety of perfluorinated allylic compounds has been developed starting from perfluoroalkyl iodides and allyltins. Allyltributyltin, methallyltributyltin and crotyltributyltin all proved to be useful for the transformation. The desired perfluorinated allylic compound was conveniently isolated from the crude mixture by solid-phase extraction with fluorous reverse-phase silica (FRPS).
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1641611
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