Title of article
7,7-Dimethyl-6,8-dioxabicyclo[3.3.0]oct-3-en-2-one as a synthetic equivalent of ketodicyclopentadiene: a new route to (−)-physostigmine, (−)-physovenine, and (−)-aphanorphine
Author/Authors
Tanaka، نويسنده , , Keigo and Taniguchi، نويسنده , , Takahiko and Ogasawara، نويسنده , , Kunio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
1049
To page
1052
Abstract
A new diastereocontrolled route to three alkaloids having a quaternary benzylic stereogenic center, (−)-physostigmine, (−)-physovenine, and (−)-aphanorphine, has been developed using enantiopure 7,7-dimethyl-6,8-dioxabicyclo[3.3.0]oct-3-en-2-one as a synthetic equivalent of chiral cyclopentadienone.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1641696
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