Title of article
Facile synthesis and rearrangement of propargylic trifluoromethanesulfinates
Author/Authors
Braverman، نويسنده , , Samuel and Pechenick، نويسنده , , Tatiana and Zafrani، نويسنده , , Yossi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
1391
To page
1393
Abstract
The synthesis and reactivity of propargylic trifluoromethanesulfinates under various conditions have been investigated. These esters readily undergo [2,3]-sigmatropic rearrangement to the corresponding allenyl trifluoromethyl sulfones, even under solvolytic conditions. An unusually facile nucleophilic addition of the solvent to the allenyl sulfone under the latter conditions has also been observed.
Keywords
Allenes , Rearrangements , fluorine and sulfur compounds , Acetylenes
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1642013
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