Title of article
Novel stereoselective construction of a quaternary carbon: application to synthesis of the cyclopentenedione moiety of madindolines
Author/Authors
Hosokawa، نويسنده , , Seijiro and Sekiguchi، نويسنده , , Kazuhiko and Enemoto، نويسنده , , Manabu and Kobayashi، نويسنده , , Susumu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
6429
To page
6433
Abstract
Enantioselective synthesis of the cyclopentenedione moiety of madindolines was achieved. Stereoselective construction of a quaternary carbon was realized by alkylation of an enolate possessing chiral auxiliary. Cyclopentenedione was derived from a triketone precursor by intramolecular condensation.
Keywords
madindoline , cyclopentenedione , Alkylation , quaternary carbon
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1642768
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