Title of article
Reverse Brook rearrangement of 2-alkynyl trialkylsilyl ether. Synthesis of optically active (1-hydroxy-2-alkynyl)trialkylsilane
Author/Authors
Sakaguchi، نويسنده , , Kazuhiko and Fujita، نويسنده , , Masato and Suzuki، نويسنده , , Hiroyuki and Higashino، نويسنده , , Masato and Ohfune *، نويسنده , , Yasufumi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
6589
To page
6592
Abstract
A new method for the synthesis of optically active α-hydroxyalkynylsilane 3 is described. The key step of the conversion to 3 was the use of the reverse Brook rearrangement of the 2-alkynyl silyl ether 2.
Keywords
reverse Brook rearrangement , ?-hydroxyalkynylsilane , 2-alkynyl silyl ether
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1642842
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