Title of article
Heavy cation effect on intersystem crossing between triplet and singlet phenylacyl and benzyl geminate radical pairs within zeolites
Author/Authors
Warrier، نويسنده , , Manoj and Turro، نويسنده , , Nicholas J and Ramamurthy، نويسنده , , V، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
7163
To page
7167
Abstract
The difference in product selectivity observed between dibenzyl ketones and naphthyl esters in zeolites is due to the difference in spin of the radical pairs formed from these precursors. Heavy cations present in zeolites can enhance intersystem crossing between triplet and singlet geminate radical pairs.
Keywords
Zeolite , Spin , Dibenzyl ketone , Radical pairs
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1643114
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