Title of article
A new samarium diiodide-mediated coupling reaction between N-acyl lactams and ketones or aldehydes
Author/Authors
Farcas، نويسنده , , Sorin and Namy، نويسنده , , Jean-Louis، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
4
From page
7299
To page
7302
Abstract
A new SmI2-mediated coupling reaction between N-acyl lactams and ketones or aldehydes is reported. The ring opening of these imides with samarium diiodide gives acyl samarium species, which are trapped by ketones or aldehydes to yield amido α-ketols. With an excess of SmI2, in the presence of ethanol, the end products are amidoketones.
Keywords
coupling reactions , acyl lactams , amidoketones , amidoketols , Samarium diiodide
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1643173
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