Title of article
Synthesis of spongian diterpenes: (−)-spongian-16-oxo-17-al and (−)-acetyldendrillol-1
Author/Authors
Arn?، نويسنده , , Manuel A. Gonzalez، نويسنده , , Miguel A and Mar??n، نويسنده , , M.Luisa and Zaragoz?، نويسنده , , Ram?n J، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
1669
To page
1671
Abstract
An efficient diastereoselective synthesis of the spongian diterpenes (−)-spongian-16-oxo-17-al (1) and (−)-acetyldendrillol-1 (13) is described starting from (+)-podocarp-8(14)-13-one (6) via the ester-dialdehyde 11 as key intermediate. The absolute configuration at C-17 in synthetic compound 13 has conclusively been proved by NOE experiments.
Keywords
Diterpenes , Synthesis , Sponges , podocarpenone , Marine metabolites
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1643384
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