• Title of article

    N-Fluorocinchonidinium tetrafluoroborate F-CD-BF4: purification and structure elucidation of this novel enantioselective electrophilic fluorinating agent

  • Author/Authors

    Cahard، نويسنده , , Dominique and Audouard، نويسنده , , Christophe and Plaquevent، نويسنده , , Jean-Christophe and Toupet، نويسنده , , Loic and Roques، نويسنده , , Nicolas، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    1867
  • To page
    1869
  • Abstract
    The first ever enantiopure N-fluoro quaternary ammonium salt of cinchonidine (F-CD-BF4) was prepared as an enantioselective fluorinating agent. A one-step transfer-fluorination of the quinuclidine moiety with Selectfluor® gave the [NF]+ reagent. The X-ray structure of F-CD-BF4 was determined, which shows the NF distance (1.409(7) Å) close to that found in other NF compounds.
  • Keywords
    Alkaloids , Fluorine compounds , Halogenation , X-ray crystallography , Enantioselection
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1643551

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1643551