Title of article :
An efficient stereoselective synthesis of (2S,4S,5R)-(−)-bulgecinine
Author/Authors :
Krasi?ski، نويسنده , , Antoni and Jurczak، نويسنده , , Janusz، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
N-Benzyl-N-carbobenzyloxy-O-tert-butyldimethylsilyl-d-serinal (6) was reacted under Barbier conditions with allyl bromide affording diastereoselectively (82:18) the anti-adduct 5, which was subsequently transformed into (2S,4S,5R)-(−)-bulgecinine (1).
Keywords :
amino aldehydes , Asymmetric induction , epoxidation , cyclization , Pyrrolidines , allylation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
