Title of article
Palladium catalyzed activation of borane–amine adducts: rate enhancement of amine–borane methanolysis in the reduction of nitrobenzenes to anilines
Author/Authors
Couturier، نويسنده , , Michel and Tucker، نويسنده , , John L and Andresen، نويسنده , , Brian M and Dubé، نويسنده , , Pascal and Brenek، نويسنده , , Steven J and Negri، نويسنده , , Joanna T، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
2285
To page
2288
Abstract
Hydrolytically stable borane–amines can be activated in situ through palladium catalysis and perform reductions not possible otherwise. Hence, borane–trimethylamine is an efficient hydrogen-transfer reagent for the open vessel reduction of nitroaryls to anilines. Likewise, the palladium catalyzed methanolysis/decomplexation of stable borane–amine adducts is accelerated by the action of nitrobenzene.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1643860
Link To Document