Title of article :
Palladium-tetraphosphine catalysed allylic substitution in water
Author/Authors :
Feuerstein، نويسنده , , Marie and Laurenti، نويسنده , , Dorothée and Doucet، نويسنده , , Henri and Santelli، نويسنده , , Maurice، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C3H5)]2 system catalyses allylic amination in water with very high substrate/catalyst ratio in good yields. A turnover number of 980 000 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.
Keywords :
tetraphosphine , PALLADIUM , water , allylamine , allylacetate , Allylic amination
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
